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A/C Compressor Pressure Relieve Valve, Checking

WARNING: This page is about a different car, the 2011 Volkswagen CC, 2010 Volkswagen CC, and 2009 Volkswagen CC. However, it is still accessible from the selected car via links, so may be relevant.
WARNING:

There is a danger of ice-up.

Check valve drains coolant when engine is running and pressure in coolant circuit is too high.

Turn engine off.

Checking Pressure Relief Valve On A/C Compressor (Sanden) 

Fig 1: Identifying Pressure Relief Valve On A/C Compressor (Sanden)
GWWN87-10237Courtesy of VOLKSWAGEN UNITED STATES, INC.

A/C Compressor Pressure Relief Valve 

Fig 2: Identifying A/C Compressor Pressure Relief Valve
GWWN87-10014Courtesy of VOLKSWAGEN UNITED STATES, INC.